Use the diffusion data in the table below for atoms in iron to answer the questions that follow. Assume metastable equilibrium conditions and trace amounts of C in Fe. The gas constant in SI units is 8.314 J (mol K).
|
Diffusion |
Diffusion |
||
|
Couple |
Mechanism |
Q (J/mol) |
D0 (m2/s) |
|
C in FCC iron |
Interstitial |
1.38 × 105 |
2.3 × 10-5 |
|
C in BCC iron |
Interstitial |
8.74 × 104 |
1.1 × 10-6 |
|
Fe in FCC iron |
Vacancy |
2.79 × 105 |
6.5 × 10-5 |
|
Fe in BCC iron |
Vacancy |
2.46 × 105 |
4.1 × 10-4 |
(a) Plot the diffusion coefficient as a function of inverse temperature (1/T) showing all four diffusion couples in the table.
(b) Recall the temperatures for phase transitions in iron, and for each case, indicate on the graph the temperature range over which the diffusion data is valid.
(c) Why is the activation energy for Fe diffusion higher than that for C diffusion in iron?
(d) Why is the activation energy for diffusion higher in FCC iron when compared to BCC iron?
(e) Does C diffuse faster in FCC Fe than in BCC Fe? Support your answer with a numerical calculation and state any assumptions made.
Choose an academic level, add pages, and the paper type you want.
To reduce the cost of our essay writing services, select the lengthier deadline.
We can't believe we just said that to you.
Delivering a high-quality product at a reasonable price is not enough anymore.
That’s why we have developed 5 beneficial guarantees that will make your experience with our service enjoyable, easy, and safe.
You have to be 100% sure of the quality of your product to give a money-back guarantee. This describes us perfectly. Make sure that this guarantee is totally transparent.
Read moreEach paper is composed from scratch, according to your instructions. It is then checked by our plagiarism-detection software. There is no gap where plagiarism could squeeze in.
Read moreThanks to our free revisions, there is no way for you to be unsatisfied. We will work on your paper until you are completely happy with the result.
Read moreYour email is safe, as we store it according to international data protection rules. Your bank details are secure, as we use only reliable payment systems.
Read moreBy sending us your money, you buy the service we provide. Check out our terms and conditions if you prefer business talks to be laid out in official language.
Read more
Recent Comments